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Both are pretty diverse populations.
However, the average Mexican has a lot more Native American admixture than the average mixed-race Brazilian (who in turn has a lot more African admixture than the average Mexican).
Furthermore, I think Mexicans of Native American descent tend to have different facial features than Brazilians of Native American descent.
White Mexicans of Iberian descent can probably easily pass as white Brazilians, but apart from that, what is the percentage of Mestizos who wouldn't look foreign in Brazil (and vice-versa)?
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